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Bent's rule. Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [ 1][ 2] The rule was stated by Henry A. Bent as follows: [ 2] Atomic s ...
Propagation of uncertainty. In statistics, propagation of uncertainty (or propagation of error) is the effect of variables ' uncertainties (or errors, more specifically random errors) on the uncertainty of a function based on them. When the variables are the values of experimental measurements they have uncertainties due to measurement ...
In chemistry, the lever rule is a formula used to determine the mole fraction ( xi) or the mass fraction ( wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line. [ 1]
Second rule: the electrostatic valence rule. For a given cation, Pauling defined [2] the electrostatic bond strength to each coordinated anion as , where z is the cation charge and ν is the cation coordination number. A stable ionic structure is arranged to preserve local electroneutrality, so that the sum of the strengths of the electrostatic ...
where the final substitution, N 0 = e C, is obtained by evaluating the equation at t = 0, as N 0 is defined as being the quantity at t = 0. This is the form of the equation that is most commonly used to describe exponential decay. Any one of decay constant, mean lifetime, or half-life is sufficient to characterise the decay.
Measurement uncertainty. In metrology, measurement uncertainty is the expression of the statistical dispersion of the values attributed to a quantity measured on an interval or ratio scale. All measurements are subject to uncertainty and a measurement result is complete only when it is accompanied by a statement of the associated uncertainty ...
Limiting reagent. The limiting reagent (or limiting reactant or limiting agent) in a chemical reaction is a reactant that is totally consumed when the chemical reaction is completed. [ 1][ 2] The amount of product formed is limited by this reagent, since the reaction cannot continue without it. If one or more other reagents are present in ...
For a confidence level, there is a corresponding confidence interval about the mean , that is, the interval [, +] within which values of should fall with probability . ...